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Photophysics and Photoredox Catalysis of a Homoleptic Rhenium(I) Tris(diisocyanide) Complex

Larsen, Christopher B. and Wenger, Oliver S.. (2018) Photophysics and Photoredox Catalysis of a Homoleptic Rhenium(I) Tris(diisocyanide) Complex. Inorganic Chemistry, 57 (6). pp. 2965-2968.

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Official URL: https://edoc.unibas.ch/64613/

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Abstract

Herein a homoleptic rhenium(I) complex bearing three chelating diisocyanide ligands and its photophysical properties are communicated. The complex emits weakly from a high-energy triplet metal-to-ligand charge-transfer excited state with an 8 ns lifetime in deaerated CH3CN at 22 °C and is shown to act as an efficient photoredox catalyst comparable to [Ir(ppy)3] (ppy = 2-phenylpyridine) in representative test reactions.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Wenger)
UniBasel Contributors:Wenger, Oliver and Larsen, Christopher Bryan
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:American Chemical Society
ISSN:0020-1669
e-ISSN:1520-510X
Note:Publication type according to Uni Basel Research Database: Journal article -- The final publication is available at American Chemical Society, see DOI link
Language:English
Identification Number:
Last Modified:11 Jun 2018 13:03
Deposited On:11 Jun 2018 13:03

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