Larsen, Christopher B. and Wenger, Oliver S.. (2018) Photophysics and Photoredox Catalysis of a Homoleptic Rhenium(I) Tris(diisocyanide) Complex. Inorganic Chemistry, 57 (6). pp. 2965-2968.
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Abstract
Herein a homoleptic rhenium(I) complex bearing three chelating diisocyanide ligands and its photophysical properties are communicated. The complex emits weakly from a high-energy triplet metal-to-ligand charge-transfer excited state with an 8 ns lifetime in deaerated CH3CN at 22 °C and is shown to act as an efficient photoredox catalyst comparable to [Ir(ppy)3] (ppy = 2-phenylpyridine) in representative test reactions.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Wenger) |
|---|---|
| UniBasel Contributors: | Wenger, Oliver and Larsen, Christopher Bryan |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | American Chemical Society |
| ISSN: | 0020-1669 |
| e-ISSN: | 1520-510X |
| Note: | Publication type according to Uni Basel Research Database: Journal article -- The final publication is available at American Chemical Society, see DOI link |
| Language: | English |
| Identification Number: | |
| edoc DOI: | |
| Last Modified: | 15 Oct 2019 15:02 |
| Deposited On: | 11 Jun 2018 13:03 |
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