Simple synthetic access to [Au(IBiox)Cl] complexes

Martynova, Ekaterina A. and Zuccarello, Marco and Kronenberg, Domenic and Beliš, Marek and Czapik, Agnieszka and Zhang, Ziyun and Van Hecke, Kristof and Kwit, Marcin and Baudoin, Olivier and Cavallo, Luigi and Nolan, Steven P.. (2023) Simple synthetic access to [Au(IBiox)Cl] complexes. Dalton Transactions, 52 (22). pp. 7558-7563.

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Official URL: https://edoc.unibas.ch/94918/

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Green and sustainable access to chiral and achiral gold-IBiox complexes is reported. The gold complexes were synthesized using a simple, air-tolerant, weak base protocol carried out in a green solvent. Their catalytic activity was examined in the hydroamination of alkynes. The steric protection afforded the gold center by these ligands was quantified using the %; V; bur; model and compared with the most commonly encountered NHCs.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Synthetische Chemie (Baudoin)
UniBasel Contributors:Baudoin, Olivier and Zuccarello, Marco and Kronenberg, Domenic
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:03 Aug 2023 13:23
Deposited On:08 Jun 2023 14:17

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