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Time evolution analysis of a 2D solid-gas equilibrium: a model system for molecular adsorption and diffusion

Berner, S. and Brunner, M. and Ramoino, L. and Suzuki, H. and Güntherodt, H. -J. and Jung, T. A.. (2001) Time evolution analysis of a 2D solid-gas equilibrium: a model system for molecular adsorption and diffusion. Chemical Physics Letters, 348 (3-4). pp. 175-181.

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Official URL: https://edoc.unibas.ch/94706/

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Abstract

The adsorption of sub-phthalocyanine molecules on Ag(111) has been studied by means of scanning tunneling microscopy (STM). The molecules are observed in different two-dimensional (2D) phases of adsorption which coexist in thermodynamic equilibrium. In the condensed phase the molecules form well-ordered islands with a honeycomb pattern. In the gas phase single molecules can be discriminated in single scan lines by characteristic tip excursions which occur randomly. The energy barrier for surface diffusion as well as the condensation energy to form 2D islands is estimated and discussed. (C) 2001 Published by Elsevier Science B.V.
Faculties and Departments:05 Faculty of Science > Departement Physik > Physik
UniBasel Contributors:Jung, Thomas A.
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:0009-2614
e-ISSN:1873-4448
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Jun 2023 13:28
Deposited On:12 Jun 2023 13:28

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