Two-Dimensional Calix[4]arene-based Metal-Organic Coordination Networks of Tunable Crystallinity

Moradi, Mina and Tulli, Ludovico G. and Nowakowski, Jan and Baljozovic, Milos and Jung, Thomas A. and Shahgaldian, Patrick. (2017) Two-Dimensional Calix[4]arene-based Metal-Organic Coordination Networks of Tunable Crystallinity. Angewandte Chemie International Edition, 56 (46). pp. 14395-14399.

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Official URL: https://edoc.unibas.ch/94250/

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A flexible and versatile method to fabricate two-dimensional metal-organic coordination networks (MOCNs) by bottom-up self-assembly is described. 2D crystalline layers were formed at the air-water interface, coordinated by ions from the liquid phase, and transferred onto a solid substrate with their crystallinity preserved. By using an inherently three-dimensional amphiphile, namely 25,26,27,28-tetrapropoxycalix[4] arene-5,11,17,23-tetracarboxylic acid, and a copper metal node, large and monocrystalline dendritic MOCN domains were formed. The method described allows for the fabrication of monolayers of tunable crystallinity on liquid and solid substrates. It can be applied to a large range of differently functionalized organic building blocks, also beyond macrocycles, which can be interconnected by diverse metal nodes.
Faculties and Departments:05 Faculty of Science > Departement Physik > Physik
UniBasel Contributors:Jung, Thomas A.
Item Type:Article, refereed
Article Subtype:Research Article
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:12 Apr 2023 07:04
Deposited On:12 Apr 2023 07:04

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