Spatial Separation of the Conformers of Methyl Vinyl Ketone

Wang, Jia and Kilaj, Ardita and He, Lanhai and Dlugolecki, Karol and Willitsch, Stefan and Kuepper, Jochen. (2020) Spatial Separation of the Conformers of Methyl Vinyl Ketone. The journal of physical chemistry. A, 124 (40). pp. 8341-8345.

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Official URL: https://edoc.unibas.ch/80813/

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Methyl vinyl ketone (C4H6O) is a volatile, labile organic compound of importance in atmospheric chemistry. We prepared a molecular beam of methyl vinyl ketone with a rotational temperature of 1.2(2) K and demonstrated the spatial separation of the s-cis and s-trans conformers of methyl vinyl ketone using the electrostatic deflector. The resulting sample density was 1.5(2) x 10(8) cm(-1) for the direct beam in the laser ionization region. These conformer-selected methyl vinyl ketone samples are well suited for conformer-specific chemical reactivity studies such as in Diels-Alder cycloaddition reactions.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Chemische Physik (Willitsch)
UniBasel Contributors:Kilaj, Ardita and Willitsch, Stefan
Item Type:Article, refereed
Article Subtype:Research Article
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:17 Feb 2021 11:36
Deposited On:17 Feb 2021 11:21

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