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Transferring photocatalytic CO2 reduction mediated by Cu(N^N)(P^P)+ complexes from organic solvents into ionic liquid media

Forero-Cortés, Paola Andrea and Marx, Maximilian and Moustakas, Nikolaos G and Brunner, Fabian and Housecroft, Catherine Elizabeth and Constable, Edwin Charles and Junge, Henrik and Bellera, Matthias and Strunk, Jennifer. (2020) Transferring photocatalytic CO2 reduction mediated by Cu(N^N)(P^P)+ complexes from organic solvents into ionic liquid media. Green chemistry, 22 (14). pp. 4541-4549.

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Official URL: https://edoc.unibas.ch/77786/

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Abstract

Photocatalytic carbon dioxide reduction utilizing metal complexes based on the earth-abundant transition metals iron and copper was transferred from organic solvents into ionic liquids with high selectivity and moderate turn-over numbers. Different classes of ionic liquids were evaluated to determinate the CO/H2 selectivity of the process. High-purity conditions were utilized to validate that CO was a result of CO2 reduction and not resulting from other carbon sources. In addition, a novel copper-based photosensitizer was synthesized and its photo- and electrochemical properties were investigated.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Housecroft, Catherine Elizabeth and Constable, Edwin Charles and Brunner, Fabian and Forero Cortes, Paola Andrea
Item Type:Article, refereed
Article Subtype:Research Article
ISSN:1463-9262
e-ISSN:1463-9270
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
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Last Modified:21 Jul 2021 01:30
Deposited On:05 Aug 2020 15:44

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