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Beyond Simple Substitution Patterns âEuro" Symmetrically Tetrasubstituted [2.2]Paracyclophanes as 3D Functional Materials

Weiland, Kevin J. and Gallego, Almudena and Mayor, Marcel. (2019) Beyond Simple Substitution Patterns âEuro" Symmetrically Tetrasubstituted [2.2]Paracyclophanes as 3D Functional Materials. European Journal of Organic Chemistry, 2019 (20). pp. 3073-3085.

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Official URL: https://edoc.unibas.ch/75496/

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Abstract

[2.2]Paracyclophane is the prototypical layered hydrocarbon and has been essential for investigations of through-space electronic interactions. Over the last years more examples of tetrasubstituted derivatives have been reported. This minireview discusses the synthetic approaches towards various substitution patterns and provides a survey over different approaches used to achieve and derivatize symmetric tetrasubstitution. The first two sections of this work present homo-tetrasubstituted derivatives, while the third section gives insight into symmetrically hetero-tetrasubstituted analogues. These approaches are briefly discussed, the resulting structures are presented in detail, and their specific properties resulting from the incorporation of [2.2]paracyclophane are elucidated.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Molecular Devices and Materials (Mayor)
UniBasel Contributors:Mayor, Marcel and Weiland, Kevin and Gallego Gonzalez, Almudena
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:1434-193X
e-ISSN:1099-0690
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
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Last Modified:18 Mar 2020 12:17
Deposited On:21 Feb 2020 13:07

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