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Luminescent Ni(0) complexes

Malzkuhn, Sabine and Wenger, Oliver S.. (2018) Luminescent Ni(0) complexes. Coordination Chemistry Reviews, 359. pp. 52-56.

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Abstract

With its 3d10 valence electron configuration Ni(0) is isoelectronic with Cu(I). While many Cu(I) complexes emitting from metal-to-ligand charge transfer (MLCT) excited states have been explored, the number of luminescent Ni(0) complexes known to date is very limited. Ni(0) is typically stabilized by carbonyls, phosphines or isocyanides due to the π-acceptor properties of these ligands, and photoluminescence has been reported in a few selected cases that are reviewed herein. Recent studies indicate that chelating isocyanide ligands are promising for obtaining Ni(0) complexes with long-lived 3MLCT states, and this could be interesting for a similar range of applications as with photoactive Cu(I) complexes, including for example luminescent devices, solar cells, and organic photoredox reactions.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Wenger)
UniBasel Contributors:Wenger, Oliver and Malzkuhn, Sabine
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:0010-8545
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Last Modified:11 Jun 2018 12:55
Deposited On:11 Jun 2018 12:55

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