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Photoredox Catalysis with Metal Complexes Made from Earth-Abundant Elements

Larsen, Christopher B. and Wenger, Oliver S.. (2018) Photoredox Catalysis with Metal Complexes Made from Earth-Abundant Elements. Chemistry - A European Journal, 24 (9). pp. 2039-2058.

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Official URL: https://edoc.unibas.ch/64599/

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Abstract

Photoredox chemistry with metal complexes as sensitizers and catalysts frequently relies on precious elements such as ruthenium or iridium. Over the past 5 years, important progress towards the use of complexes made from earth‐abundant elements in photoredox catalysis has been made. This review summarizes the advances made with photoactive CrIII, FeII, CuI, ZnII, ZrIV, Mo0, and UVI complexes in the context of synthetic organic photoredox chemistry using visible light as an energy input. Mechanistic considerations are combined with discussions of reaction types and scopes. Perspectives for the future of the field are discussed against the background of recent significant developments of new photoactive metal complexes made from earth‐abundant elements.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Wenger)
UniBasel Contributors:Wenger, Oliver and Larsen, Christopher Bryan
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:0947-6539
e-ISSN:1521-3765
Note:Publication type according to Uni Basel Research Database: Journal article -- The final publication is available at wiley, see DOI link
Language:English
Identification Number:
Last Modified:11 Jun 2018 12:28
Deposited On:11 Jun 2018 12:28

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