Bachmann, Daniel G. and Wittwer, Christopher C. and Gillingham, Dennis G.. (2013) Stereoselective Heck Reactions with Vinyl Sulfoxides, Sulfides and Sulfones. Advanced Synthesis and Catalysis, 355 (18). pp. 3703-3707.
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Official URL: http://edoc.unibas.ch/dok/A6223563
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Abstract
We report the Heck cross-coupling of notoriously unreactive, but synthetically valuable olefins: vinyl sulfoxides, vinyl sulfones, and vinyl sulfides. Key findings include the importance of the sterically hindered (tri-tert-butyl)phosphine ligand and the unique effectiveness of triethylamine as the base. The method is general, E-selective, and can be used to synthesize disubstituted or trisubstituted olefins through simple adjustments of stoichiometry.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Organische Chemie (Gillingham) |
|---|---|
| UniBasel Contributors: | Gillingham, Dennis |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 1615-4150 |
| e-ISSN: | 1615-4169 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: | |
| Last Modified: | 17 Mar 2017 13:25 |
| Deposited On: | 27 Feb 2014 15:46 |
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