Pischl, Matthias C. and Weise, Christian F. and Müller, Marc-André and Pfaltz, Andreas and Schneider, Christoph. (2013) A convergent and stereoselective synthesis of the glycolipid components phthioceranic acid and hydroxyphthioceranic acid. Angewandte Chemie International Edition, 52 (34). pp. 8968-8972.
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Official URL: http://edoc.unibas.ch/dok/A6212004
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Abstract
Simply convergent: The polydeoxypropionates 1 and 2 are important constituents of the cell wall of Mycobacterium tuberculosis. Key steps in their total synthesis include two Suzuki–Miyaura cross-coupling reactions and two highly diastereoselective iridium-catalyzed hydrogenations. The trideoxypropionates employed as central building blocks were prepared by sequential oxy-Cope rearrangement, hydrogenation, and enolate methylation.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Synthetische organische Chemie (Pfaltz) |
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| UniBasel Contributors: | Pfaltz, Andreas and Müller, Marc-André |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 1433-7851 |
| e-ISSN: | 1521-3773 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 10 Apr 2017 08:53 |
| Deposited On: | 31 Jan 2014 09:51 |
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