Chapelat, Julien and Chougnet, Antoinette and Woggon, Wolf-D.. (2009) Biomimetic chromanol cyclisation : a common route to to α-Tocotrienol and α-Tocopherol. European journal of organic chemistry, 2009, H. 13. pp. 2069-2076.
Full text not available from this repository.
Official URL: http://edoc.unibas.ch/dok/A5260116
Downloads: Statistics Overview
Abstract
A common synthetic route to alpha-tocotrienol and alpha-tocopherol has been accomplished by a biomimetic cyclization that yields the chromanol ring. The chirality at C2 of the chromanol was induced by a covalently attached chiral dipeptide. Its terminal Asp participates in the enantioface-selective protonation of the double bond of the alpha-tocotrienol precursor I. alpha-Tocotrienol was diastereoselectively hydrogenated to alpha-tocopherol.
| Faculties and Departments: | 05 Faculty of Science 05 Faculty of Science > Departement Chemie > Chemie |
|---|---|
| UniBasel Contributors: | Woggon, Wolf-Dietrich |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley-VCH Verlag |
| ISSN: | 1434-193X |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Last Modified: | 22 Mar 2012 14:29 |
| Deposited On: | 22 Mar 2012 14:06 |
Repository Staff Only: item control page