Therrien, Bruno and Ward, Thomas R.. (1999) Synthesis of a Configurationally Stable Three-Legged Piano-Stool Complex. Angewandte Chemie International Edition, 38 (3). pp. 405-408.
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Official URL: http://edoc.unibas.ch/dok/A5254483
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Abstract
NA transition metal Lewis acid with metal-centered chirality is obtained by η6:η1:η1 coordination of a 1,3-disubstituted arene with a phosphane and a pyrazole tether (PArN) to ruthenium. The three-legged piano-stool complex [{η6:η1:η1-(PArN)}Ru(H2O)]2+ (structure depicted) displays remarkable configurational stability. Its planar chiral, neutral precursor [{η6:η1-(PArN)}RuCl2] can be resolved by preparative HPLC.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward) |
|---|---|
| UniBasel Contributors: | Ward, Thomas R. R. |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 1433-7851 |
| e-ISSN: | 1521-3773 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: | |
| Last Modified: | 24 Apr 2017 14:42 |
| Deposited On: | 22 Mar 2012 14:07 |
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