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A non-iterative, flexible, and highly stereoselective synthesis of polydeoxypropionates - synthesis of (+)-vittatalactone.

Weise, Christian F. and Pischl, Matthias and Pfaltz, Andreas and Schneider, Christioph. (2011) A non-iterative, flexible, and highly stereoselective synthesis of polydeoxypropionates - synthesis of (+)-vittatalactone. Chemical Communications, 47 (11). pp. 3248-3250.

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Official URL: http://edoc.unibas.ch/46563/

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Abstract

A short sequence comprising an oxy-Cope rearrangement, iridium-catalyzed hydrogenation, and enolate methylation provides trideoxypropionates with excellent diastereocontrol. A straightforward synthesis of the cucumber beetle pheromone (+)-vittatalactone illustrates this new strategy.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Synthetische organische Chemie (Pfaltz)
UniBasel Contributors:Pfaltz, Andreas
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
ISSN:1359-7345
e-ISSN:1364-548X
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:19 Dec 2016 15:13
Deposited On:19 Dec 2016 15:10

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