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Controlling the Dimensionality of On-Surface Coordination Polymers via Endo- or Exoligation

Shchyrba, Aneliia and Wäckerlin, Christian and Nowakowski, Jan and Nowakowska, Sylwia and Björk, Jonas and Fatayer, Shadi and Girovsky, Jan and Nijs, Thomas and Martens, Susanne C. and Kleibert, Armin and Stöhr, Meike and Ballav, Nirmalya and Jung, Thomas A. and Gade, Lutz H.. (2014) Controlling the Dimensionality of On-Surface Coordination Polymers via Endo- or Exoligation. Journal of the American Chemical Society, 136 (26). pp. 9355-9363.

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Abstract

The formation of on-surface coordination polymers is controlled by the interplay of chemical reactivity and structure of the building blocks, as well as by the orientating role of the substrate registry. Beyond the predetermined patterns of structural assembly, the chemical reactivity of the reactants involved may provide alternative pathways in their aggregation. Organic molecules, which are transformed in a surface reaction, may be subsequently trapped via coordination of homo- or heterometal adatoms, which may also play a role in the molecular transformation. The amino-functionalized perylene derivative, 4,9-diaminoperylene quinone-3,10-diimine (DPDI), undergoes specific levels of dehydrogenation (-1 H2 or -3 H2) depending on the nature of the present adatoms (Fe, Co, Ni or Cu). In this way, the molecule is converted to an endo- or an exoligand, possessing a concave or convex arrangement of ligating atoms, which is decisive for the formation of either 1D or 2D coordination polymers.
Faculties and Departments:05 Faculty of Science > Departement Physik > Physik
UniBasel Contributors:Jung, Thomas A.
Item Type:Article, refereed
Publisher:American Chemical Society
ISSN:0002-7863
e-ISSN:1520-5126
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:05 Oct 2017 14:45
Deposited On:25 Oct 2016 13:44

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