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Formation of a [2+2]-heterotetranuclear macrocycle from reaction of a platina-homoditopic ligand with iron(II)

Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, M. and Schaffner, S. and Shardlow, E. J.. (2005) Formation of a [2+2]-heterotetranuclear macrocycle from reaction of a platina-homoditopic ligand with iron(II). Dalton Transactions, 2. pp. 234-235.

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Official URL: http://edoc.unibas.ch/39195/

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Abstract

Reaction of 4`-(2-propyn-1-oxy)-2,2`:6`,2``-terpyridine (HC= CCH(2)Oterpy) with trans-[PtI2(PEt3)(2)] regioselectively metallates the alkyne to give trans-[Pt(C=CCH(2)Oterpy)(2)(PEt3)(2)] which, when treated with Fe(II), gives a [2 + 2]-metallocycle.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Publisher:Royal Society of Chemistry
ISSN:1477-9226
e-ISSN:1477-9234
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 08:48
Deposited On:03 Feb 2016 09:13

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