Tiefenbacher, Konrad and Puigcerver, Julio and Trapp, Nils and Strassberger, Alexander Felix and Zengaffinen, Michael David. (2024) Quinoacridane[4]arenes─Very Large Conformationally Restricted Macrocycles. Organic Letters, 26 (31). 6720–6724.
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Abstract
Phenol-based macrocycles play a fundamental role in supramolecular chemistry, but their size has been rather limited. Here we report a novel class of very large, bowl-shaped macrocycles with a diameter of 21.8 Å. These quinoacridane[4]arenes are 150% larger than the current record holders, the acridane[4]arenes, and three times the size of resorcin[4]arene. We expect the quinoacridane[4]arenes to be a useful platform for the construction of molecular containers.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Synthesis of Functional Modules (Tiefenbacher) |
|---|---|
| UniBasel Contributors: | Tiefenbacher, Konrad |
| Item Type: | Article |
| Article Subtype: | Further Journal Contribution |
| Publisher: | American Chemical Society |
| ISSN: | 1523-7060 |
| e-ISSN: | 1523-7052 |
| Language: | English |
| Identification Number: | |
| edoc DOI: | |
| Last Modified: | 21 Aug 2024 06:23 |
| Deposited On: | 21 Aug 2024 06:23 |
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