Constable, Edwin C. and Housecroft, Catherine E. and Johnston, Lesley A. and Armspach, D. and Neuburger, M. and Zehnder, M.. (2001) Dicobalt cluster functionalized 2,2′:6′,2″-terpyridine ligands and their ruthenium(II) complexes. Polyhedron, 20 (6). pp. 483-492.
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Abstract
A series of 2.2`:6`.2``-terpyridine (tpy) ligands functionalized in the 4`-position with alkyne substituents has been prepared and characterized. Treatment of these ligands with [RuCl3(tpy)] yields complexes with pendant alkyne groups which then readily react with Co-2(CO)(8) to give novel compounds containing both cluster and classical coordination motifs. The new compounds are characterized by mass spectrometric and spectroscopic methods, and the single crystal structure of [Ru(tpy)(4`-HC=CCH(2)Otpy)][PF6](2) is reported. (C) 2001 Elsevier Science B.V. All rights reserved.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable) |
|---|---|
| UniBasel Contributors: | Constable, Edwin Charles |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Elsevier |
| ISSN: | 0277-5387 |
| e-ISSN: | 1873-3719 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: | |
| Last Modified: | 19 Jan 2023 13:34 |
| Deposited On: | 19 Jan 2023 13:34 |
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