Schmidt, Tanno A. and Sparr, Christof. (2022) Photocatalytic deracemisation of cobalt(III) complexes with fourfold stereogenicity. Chemical Communications , 58 (87). pp. 12172-12175.
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Abstract
The deracemisation of fourfold stereogenic cobalt(III) diketonates with a chiral photocatalyst is described. With only 0.5 mol% menthyl Ru(bpy); 3; 2+; photocatalyst, an enantiomeric enrichment of up to 88 : 12 e.r. was obtained for the major meridional diastereomers. Moreover, a distribution of configurationally stable diastereomers distinct from the thermodynamic ratio was observed upon reaching the photostationary state.
Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Organische Chemie (Sparr) |
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UniBasel Contributors: | Sparr, Christof |
Item Type: | Article, refereed |
Article Subtype: | Research Article |
Publisher: | Royal Society of Chemistry |
ISSN: | 1359-7345 |
e-ISSN: | 1364-548X |
Note: | Publication type according to Uni Basel Research Database: Journal article |
Language: | English |
Identification Number: |
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edoc DOI: | |
Last Modified: | 16 Nov 2022 08:04 |
Deposited On: | 16 Nov 2022 08:04 |
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