Electron Transfer across o-Phenylene Wires

Photoinduced electron transfer across rigid rod-like oligo-p-phenylenes has been thoroughly investigated in the past, but their o-connected counterparts are yet entirely unexplored in this regard. We report on three molecular dyads comprised of a triarylamine donor and a Ru(bpy)32+ (bpy =2,2′-bipyridine) acceptor connected covalently by 2 to 6 o-phenylene units. Pulsed excitation of the Ru(II) sensitizer at 532 nm leads to the rapid formation of oxidized triarylamine and reduced ruthenium complex via intramolecular electron transfer. The subsequent thermal reverse charge-shift reaction to reinstate the electronic ground-state occurs on a time scale of 120–220 ns in deaerated CH3CN at 25 °C. The conformational flexibility of the o-phenylene bridges causes multiexponential transient absorption kinetics for the photoinduced forward process, but the thermal reverse reaction produces single-exponential transient absorption decays. The key finding is that the flexible o-phenylene bridges permit rapid formation of photoproducts storing ca. 1.7 eV of energy with lifetimes on the order of hundreds of nanoseconds, similar to what is possible with rigid rod-like donor–acceptor compounds. Thus, the conformational flexibility of the o-phenylenes represents no disadvantage with regard to the photoproduct lifetimes, and this is relevant in the greater context of light-to-chemical energy conversion.