Royal, Titouan and Baudoin, Olivier. (2019) Pd-catalyzed gamma-arylation of gamma,delta-unsaturated O-carbamates via an unusual haptotropic rearrangement. Chemical Science, 10 (8). pp. 2331-2335.
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Abstract
An unusual gamma-selectivity was observed in the arylation of gamma,delta-unsaturated O-carbamates involving directed lithiation, transmetallation to zinc and Negishi coupling, when a specific combination of aryl electrophile and phosphine ligand is employed. Mechanistic studies indicate that an unusual, stereospecific haptotropic rearrangement of the palladium-diene intermediate is involved.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Synthetische Chemie (Baudoin) |
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| UniBasel Contributors: | Baudoin, Olivier |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 2041-6520 |
| e-ISSN: | 2041-6539 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Language: | English |
| Identification Number: |
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| edoc DOI: | |
| Last Modified: | 09 Oct 2019 13:06 |
| Deposited On: | 09 Oct 2019 13:06 |
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