Markert, Christian and Neuburger, Markus and Kulicke, Klaus and Meuwly, Markus and Pfaltz, Andreas. (2007) Palladium-catalyzed allylic substitution: reversible formation of allyl-bridged dinuclear palladium(I) complexes. Angewandte Chemie International Edition, 46 (31). pp. 5892-5895.
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Official URL: http://edoc.unibas.ch/dok/A5250876
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Abstract
ESI-MS monitoring of the title reaction has led to the discovery that dinuclear allyl-bridged PdI complexes are formed reversibly in substantial amounts during catalysis (see scheme; Bz=benzoyl). The structure of one such complex was determined by X-ray analysis (see picture; P yellow, N blue, O red, Pd dark gray). Upon consumption of the starting materials a new dinuclear complex resulting from reductive C[BOND]Cl bond cleavage of CH2Cl2 was observed.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Physikalische Chemie (Meuwly) |
|---|---|
| UniBasel Contributors: | Meuwly, Markus |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 1433-7851 |
| e-ISSN: | 1521-3773 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 10 Apr 2017 13:35 |
| Deposited On: | 22 Mar 2012 13:33 |
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