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Chemically controlled conductivity : torsion-angle dependence in a single-molecule biphenyldithiol junction

Vonlanthen, David and Mishchenko, Artem and Elbing, Mark and Neuburger, Markus and Wandlowski, Thomas and Mayor, Marcel. (2009) Chemically controlled conductivity : torsion-angle dependence in a single-molecule biphenyldithiol junction. Angewandte Chemie International Edition, 48 (47). pp. 8886-8890.

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Official URL: http://edoc.unibas.ch/dok/A5259892

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Abstract

Stepwise regulation of the molecular conductance was observed in a series of eight biphenyldithiols with fixed torsion angles between the phenyl rings. These compounds were synthesized and their single-molecule conductance was investigated in an STM junction. A cos2 dependence was found between the interplane torsion angle and the single-molecule conductivity (see plot).
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Molecular Devices and Materials (Mayor)
UniBasel Contributors:Mayor, Marcel and Vonlanthen, David
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:1433-7851
e-ISSN:1521-3773
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:05 Apr 2017 14:14
Deposited On:22 Mar 2012 13:33

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