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Iridium-Catalyzed Enantioselective Hydrogenation of Vinylsilanes

Wang, Aie and Bernasconi, Maurizio and Pfaltz, Andreas. (2017) Iridium-Catalyzed Enantioselective Hydrogenation of Vinylsilanes. Advanced Synthesis and Catalysis, 359 (15). pp. 2523-2529.

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Official URL: http://edoc.unibas.ch/58829/

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Abstract

We have screened a diverse array of iridium complexes derived from chiral N,P ligands as catalysts for the asymmetric hydrogenation of vinylsilanes, a transformation for which generally applicable catalysts were lacking. Several catalysts emerged from this study that enabled the highly enantioselective hydrogenation of a wide range of vinylsilanes with trisubstituted or disubstituted terminal C=C bonds bearing aryl, alkyl, ethoxycarbonyl, or hydroxymethyl substituents. In addition to trimethylsilyl and dimethyl(phenyl) silyl derivatives, trialkoxysilyl- and silacyclobutyl-substituted alkenes were used as substrates.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Synthetische organische Chemie (Pfaltz)
UniBasel Contributors:Pfaltz, Andreas
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:1615-4150
e-ISSN:1615-4169
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:15 Jan 2018 10:10
Deposited On:15 Jan 2018 10:10

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