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Luminescent complexes made from chelating isocyanide ligands and earth-abundant metals

Büldt, Laura A. and Wenger, Oliver S.. (2017) Luminescent complexes made from chelating isocyanide ligands and earth-abundant metals. Dalton Transactions, 46. pp. 15175-15177.

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Abstract

In this invited frontier article, recently discovered d6 and d10 complexes with long-lived metal-to-ligand charge transfer (MLCT) excited states are highlighted. Chelating diisocyanide ligands give access to emissive Mo(0) and Cr(0) complexes with d6 electron configuration exhibiting photophysical properties similar to those of Ru(II) polypyridines or cyclometalated Ir(III) complexes. With Ni(0), these ligands yield luminescent tetrahedral d10 complexes similar to isoelectronic Cu(I) bis(diimine) compounds.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Wenger)
UniBasel Contributors:Wenger, Oliver and Büldt, Laura Allegra
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
ISSN:1477-9226
e-ISSN:1477-9234
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:02 Jul 2019 08:20
Deposited On:27 Dec 2017 14:15

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