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Chromium(0), Molybdenum(0), and Tungsten(0) Isocyanide Complexes as Luminophores and Photosensitizers with Long-Lived Excited States

Büldt, Laura A. and Wenger, Oliver S.. (2017) Chromium(0), Molybdenum(0), and Tungsten(0) Isocyanide Complexes as Luminophores and Photosensitizers with Long-Lived Excited States. Angewandte Chemie International Edition, 56 (21). pp. 5676-5682.

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Official URL: http://edoc.unibas.ch/58018/

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Abstract

Arylisocyanide complexes based on earth-abundant Group 6 d6 metals are interesting alternatives to photoactive complexes made from precious metals such as RuII, ReI, OsII, or IrIII. Some of these complexes have long-lived 3MLCT excited states that exhibit luminescence with good quantum yields as well as nano- to microsecond lifetimes, and they are very strongly reducing. Recent studies have demonstrated that Cr0, Mo0, and W0 arylisocyanide complexes have great potential for applications in luminescent devices, photoredox catalysis, and dye-sensitized solar cells.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Wenger)
UniBasel Contributors:Wenger, Oliver and Büldt, Laura Allegra
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:1433-7851
e-ISSN:1521-3773
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:27 Dec 2017 13:52
Deposited On:27 Dec 2017 13:52

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