Royal, Titouan and Baumgartner, Yann and Baudoin, Olivier. (2017) Enantioselective α-Arylation of O-Carbamates via Sparteine-Mediated Lithiation and Negishi Cross-Coupling. Organic Letters, 19 (1). pp. 166-169.
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Abstract
A general and highly enantioselective arylation of carbamates derived from primary alcohols was developed by combining Hoppe’s sparteine-mediated asymmetric lithiation with Negishi cross-coupling. Coupled with Aggarwal’s lithiation–borylation sequence, the current method provides a short and divergent access to a variety of enantioenriched secondary and tertiary benzylic alcohols.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Synthetische Chemie (Baudoin) |
|---|---|
| UniBasel Contributors: | Baudoin, Olivier |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | American Chemical Society |
| ISSN: | 1523-7060 |
| e-ISSN: | 1523-7052 |
| Note: | Publication type according to Uni Basel Research Database: Journal article -- The final publication is available at ACS, see DOI link |
| Language: | English |
| Identification Number: | |
| edoc DOI: | |
| Last Modified: | 17 Aug 2018 12:07 |
| Deposited On: | 20 Dec 2017 08:38 |
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