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Electronic spectroscopy of resonance-stabilised C6H7 radicals

Maity, Surajit and Steglich, Mathias and Maier, John P.. (2016) Electronic spectroscopy of resonance-stabilised C6H7 radicals. Molecular Physics, 114 (19). pp. 2808-2816.

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Abstract

Electronic spectra of C6H7 radicals, α-hydrofulvenyl and cis/trans-1-vinyl-3-methylpropargyl, have been measured in the gas phase. A resonant two-colour, two-photon ionisation scheme was used after the radicals were produced in a supersonically cooled discharge source. The origin bands in D1 (2A″) ← D0 (2A″) transitions are observed at 18,734, 21,278 and 21,698 cm−1, respectively. The assignment of the spectra is based on the calculated harmonic frequencies in the D1 states and the available literature data.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Physikalische Chemie (Maier)
UniBasel Contributors:Maier, John Paul and Maity, Surajit and Steglich, Mathias
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Taylor & Francis
ISSN:0026-8976
e-ISSN:1362-3028
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:23 Feb 2017 15:37
Deposited On:23 Feb 2017 15:36

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