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Light-Driven Electron Accumulation in a Molecular Pentad

Orazietti, Margherita and Kuss-Petermann, Martin and Hamm, Peter and Wenger, Oliver S.. (2016) Light-Driven Electron Accumulation in a Molecular Pentad. Angewandte Chemie International Edition, 55 (32). pp. 9407-9410.

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Official URL: http://edoc.unibas.ch/52003/

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Abstract

Accumulation and temporary storage of redox equivalents with visible light as an energy input is of pivotal importance for artificial photosynthesis because key reactions, such as CO2 reduction or water oxidation, require the transfer of multiple redox equivalents. We report on the first purely molecular system, in which a long-lived charge-separated state (τ≈870 ns) with two electrons accumulated on a suitable acceptor unit can be observed after excitation with visible light. Importantly, no sacrificial reagents were employed.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Wenger)
UniBasel Contributors:Wenger, Oliver and Kuss-Petermann, Martin
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:1433-7851
e-ISSN:1521-3773
Note:Publication type according to Uni Basel Research Database: Journal article -- The final publication is available at Wiley, see DOI link
Language:English
Identification Number:
Last Modified:11 Jun 2018 09:18
Deposited On:11 Jan 2017 14:47

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