Nowakowski, Jan and Wäckerlin, Christian and Girovsky, Jan and Siewert, Dorota and Jung, Thomas A. and Ballav, Nirmalya. (2013) Porphyrin metalation providing an example of a redox reaction facilitated by a surface reconstruction. Chemical Communications , 49 (23). pp. 2347-2349.
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Abstract
The presence of an oxygen reconstruction on the Cu(001) surface results in the self-metalation of 5,10,15,20-tetraphenylporphyrin (2HTPP) below room temperature (at ~285 K), in contrast to 2HTPP on the bare Cu(001) substrate, where a temperature of ~450 K is required. This study demonstrates the decisive impact of a surface reconstruction on the redox reaction in the solvent-free ultra-high vacuum environment.
| Faculties and Departments: | 05 Faculty of Science > Departement Physik > Physik |
|---|---|
| UniBasel Contributors: | Jung, Thomas A. |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Royal Society of Chemistry |
| ISBN: | |
| ISSN: | 1359-7345 |
| e-ISSN: | 1364-548X |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Language: | English |
| Identification Number: |
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| edoc DOI: | |
| Last Modified: | 18 Sep 2017 10:31 |
| Deposited On: | 27 Oct 2016 08:30 |
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