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Porphyrin metalation providing an example of a redox reaction facilitated by a surface reconstruction

Nowakowski, Jan and Wäckerlin, Christian and Girovsky, Jan and Siewert, Dorota and Jung, Thomas A. and Ballav, Nirmalya. (2013) Porphyrin metalation providing an example of a redox reaction facilitated by a surface reconstruction. Chemical Communications , 49 (23). pp. 2347-2349.

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Abstract

The presence of an oxygen reconstruction on the Cu(001) surface results in the self-metalation of 5,10,15,20-tetraphenylporphyrin (2HTPP) below room temperature (at ~285 K), in contrast to 2HTPP on the bare Cu(001) substrate, where a temperature of ~450 K is required. This study demonstrates the decisive impact of a surface reconstruction on the redox reaction in the solvent-free ultra-high vacuum environment.
Faculties and Departments:05 Faculty of Science > Departement Physik > Physik
UniBasel Contributors:Jung, Thomas A.
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
ISBN:
ISSN:1359-7345
e-ISSN:1364-548X
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:18 Sep 2017 10:31
Deposited On:27 Oct 2016 08:30

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