Constable, Edwin C. and Figgemeier, E. and Hougen, I. A. and Housecroft, Catherine E. and Neuburger, M. and Schaffner, S. and Whall, L. A.. (2005) Hairpin helicates: a missing link between double-helicates and trefoil knots. Dalton Transactions, 7. pp. 1168-1175.
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Official URL: http://edoc.unibas.ch/39191/
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Abstract
We have prepared a novel ligand in which two qpy metal-binding domains are linked by a polyoxyethylene spacer. The new ligand reacts with copper(II) salts to form dinuclear double helicates with a hairpin structure. The hairpin complex and a model complex have been structurally characterised. The hairpin structure is formed regioselectively as the head-to-tail (HT) stereoisomer. Detailed electrochemical and spectroelectrochemical studies of the complexes are reported.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable) 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Housecroft) |
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| UniBasel Contributors: | Constable, Edwin Charles |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1477-9226 |
| e-ISSN: | 1477-9234 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 12 Apr 2017 08:46 |
| Deposited On: | 03 Feb 2016 09:01 |
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