edoc

Linear and macrocyclic ruthenium(II) complexes containing bis(2,2 `: 6 `,2 ``-terpyridine) ligands with flexible, naphthalene-centred spacers

Chow, Hoi Shan and Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia. (2006) Linear and macrocyclic ruthenium(II) complexes containing bis(2,2 `: 6 `,2 ``-terpyridine) ligands with flexible, naphthalene-centred spacers. Polyhedron, 25 (8). pp. 1831-1843.

Full text not available from this repository.

Official URL: http://edoc.unibas.ch/39173/

Downloads: Statistics Overview

Abstract

The syntheses and characterization of six ditopic ligands which contain polyethyleneoxy-substituted naphthalene spacers connecting two 2,2`:6`,2 ``-terpyridine metal-binding domains are described. The ligands, L, have been used to prepare two series of ruthenium(II) complexes: linear complexes of type [(tpy)Ru(L)Ru(tpy)](4+) were prepared as models for polymeric species, and metallomacrocyclic species [RunLn](2n+) (n = 2 or 3). Single crystal structures of a representative ligand and macrocyclic Ru(II) complex are reported.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:0277-5387
e-ISSN:1873-3719
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 07:44
Deposited On:26 Jan 2016 09:19

Repository Staff Only: item control page