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An evaluation of the relationship between two- and three-dimensional packing in self-organised monolayers and bulk crystals of amphiphilic 2,2 ': 6 ',2 ''-terpyridines

Constable, Edwin C. and Guentherodt, H. -J. and Housecroft, Catherine E. and Merz, Leo and Neuburger, Markus and Schaffner, Silvia and Tao, Yaqiu. (2006) An evaluation of the relationship between two- and three-dimensional packing in self-organised monolayers and bulk crystals of amphiphilic 2,2 ': 6 ',2 ''-terpyridines. New Journal of Chemistry, 30 (10). pp. 1470-1479.

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Official URL: http://edoc.unibas.ch/39169/

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Abstract

2,2 ': 6 ',2 ''-Terpyridine (tpy) ligands with pendant octadecyloxy, 4-octyloxyphenyl or 4-octadecyloxyphenyl substituents at the 4`-position have been prepared and structurally characterised. Monolayers of the compounds have been prepared on highly oriented pyrolytic graphite (HOPG) and investigated by STM. The monolayer structure corresponds to the bulk crystal structure if the latter contains planar sheets. The tpy ligands are prochiral and form homochiral domains within the monolayer, providing a spectacular visual representation of the symmetry-breaking concomitant with the formation of a monolayer.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
ISSN:1144-0546
e-ISSN:1369-9261
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 07:48
Deposited On:26 Jan 2016 08:27

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