Kajetanowicz, Anna and Chatterjee, Anamitra and Reuter, Raphael and Ward, Thomas R.. (2014) Biotinylated Metathesis Catalysts: Synthesis and Performance in Ring Closing Metathesis. Catalysis Letters, 144 (3). pp. 373-379.
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Official URL: http://edoc.unibas.ch/dok/A6338942
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Abstract
Nine biotinylated Grubbs–Hoveyda and Grubbs-type metathesis catalysts were synthesized and evaluated in ring closing metathesis reactions of N-tosyl diallylamine and 5-hydroxy-2-vinylphenyl acrylate. Their catalytic activity in organic- and aqueous solvents was compared with the second generation Grubbs–Hoveyda catalyst. The position of the biotin-moiety on the N-heterocyclic carbene was found to critically influence the catalytic activity of the corresponding ruthenium-based catalysts.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward) |
|---|---|
| UniBasel Contributors: | Chatterjee, Anamitra and Reuter, Raphael and Ward, Thomas R. R. |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Springer |
| ISSN: | 1011-372X |
| e-ISSN: | 1572-879X |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Last Modified: | 24 Apr 2017 10:05 |
| Deposited On: | 06 Mar 2015 07:44 |
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