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Light-induced reversible modification of the work function of a new perfluorinated biphenyl azobenzene chemisorbed on Au (111)

Masillamani, Appan Merari and Osella, Silvio and Liscio, Andrea and Fenwick, Oliver and Reinders, Federica and Mayor, Marcel and Palermo, Vincenzo and Cornil, Jerome and Samori, Paolo. (2014) Light-induced reversible modification of the work function of a new perfluorinated biphenyl azobenzene chemisorbed on Au (111). Nanoscale, 6 (15). pp. 8969-8977.

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Official URL: http://edoc.unibas.ch/dok/A6337621

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Abstract

We describe the synthesis of a novel biphenyl azobenzene derivative exhibiting: (i) a protected thiol anchoring group in the [small alpha]-position to readily form self-assembled monolayers (SAMs) on Au surfaces; and (ii) a terminal perfluorinated benzene ring in the [small omega]-position to modify the surface properties. The design of this molecule ensured both an efficient in situ photoswitching between the trans and cis isomers when chemisorbed on Au(111),
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Molecular Devices and Materials (Mayor)
UniBasel Contributors:Mayor, Marcel
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:RSC Publishing
ISSN:2040-3364
e-ISSN:2040-3372
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:30 Mar 2017 13:01
Deposited On:06 Feb 2015 09:59

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