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The electronic transition of AgS

Varun Gupta, and Fabio J. Mazzotti, and Corey A. Rice, and Ramya Nagarajan, and John P. Maier, . (2013) The electronic transition of AgS. Journal of molecular spectroscopy, Vol. 286/287. pp. 52-55.

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Official URL: http://edoc.unibas.ch/dok/A6194507

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Abstract

The near-infrared electronic transition of silver monosulfide, AgS was measured for the first time using mass-resolved 1+1′ resonance enhanced ionization spectroscopy in the 10 000–11 000 cm−1 region. The observed vibronic bands were analysed to obtain and for the ground state, and , for the excited state of 107Ag32 S. The transitions are assigned to the A2Σ+–X2Πi system based on the rotational analysis of the Ω″=3/2 spin–orbit component of the 0–0 and 1–0 vibronic bands. The rotational constants for the X2Π state were determined to be , and .
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Physikalische Chemie (Maier)
UniBasel Contributors:Maier, John Paul and Gupta, Varun and Rice, Corey Allen and Mazzotti, Fabio Jerome and Nagarajan, Ramya
Item Type:Article, refereed
Article Subtype:Research Article
Bibsysno:Link to catalogue
Publisher:Academic Press
ISSN:0022-2852
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:06 Dec 2013 09:35
Deposited On:06 Dec 2013 09:35

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