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Mechanistic Diversity in Proton-Coupled Electron Transfer between Thiophenols and Photoexcited [Ru(2,2′-Bipyrazine)3]2+

Kuss-Petermann, Martin and Wenger, Oliver S.. (2013) Mechanistic Diversity in Proton-Coupled Electron Transfer between Thiophenols and Photoexcited [Ru(2,2′-Bipyrazine)3]2+. Journal of Physical Chemistry Letters, 4 (15). pp. 2535-2539.

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Official URL: http://edoc.unibas.ch/dok/A6165146

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Abstract

Proton-coupled electron transfer (PCET) with phenols has been investigated in considerable detail in recent years while at the same time analogous mechanistic studies of PCET with thiophenols have remained scarce. We report on PCET between a series of thiophenols and a photoexcited Ru(II) complex, which acts as a combined electron/proton acceptor. Depending on the exact nature of the thiophenol, PCET occurs through different reaction mechanisms. The results are discussed in the context of recent studies of PCET between phenols and photoexcited d6 metal complexes.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Wenger)
UniBasel Contributors:Wenger, Oliver
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:American Chemical Society
e-ISSN:1948-7185
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:03 May 2017 11:48
Deposited On:13 Sep 2013 07:57

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