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Iridium-Catalyzed Enantioselective Hydrogenation of Alkenylboronic Esters

Ganic, Adnan and Pfaltz, Andreas. (2012) Iridium-Catalyzed Enantioselective Hydrogenation of Alkenylboronic Esters. Chemistry - A European Journal, 18 (22). pp. 6724-6728.

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Official URL: http://edoc.unibas.ch/dok/A6083391

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Abstract

Choose the right ligand: An iridium complex derived from a phosphino–imidazoline ligand is a highly efficient catalyst for the asymmetric hydrogenation of terminal vinyl boronic esters (see scheme). On the other hand, trisubstituted alkenyl-boronates can be reduced with high activity and good to excellent enantioselectivity employing a pyridine–phosphinite ligand.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Synthetische organische Chemie (Pfaltz)
UniBasel Contributors:Pfaltz, Andreas
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:0947-6539
e-ISSN:1521-3765
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 09:03
Deposited On:24 May 2013 09:03

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