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Bucky-blocks : templating a coordination network with C-60

Constable, Edwin C. and Zhang, Guoqi and Housecroft, Catherine E. and Zampese, Jennifer A.. (2012) Bucky-blocks : templating a coordination network with C-60. CrystEngComm, 14 (5). pp. 1770-1774.

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Official URL: http://edoc.unibas.ch/dok/A6056198

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Abstract

The reaction of NiCl2 center dot 6H(2)O with 4`-tert-butyl-4,2`:6`,4 ``-terpyridine (1) in MeOH/1,2-Cl2C6H4 leads to the formation of the 2-dimensional coordination polymer 4[Ni2Cl4(1)(4)]center dot 13(1,2-Cl2C6H4)center dot 30H(2)O. Each sheet comprises [4 + 4] macrocycles interconnected by octahedral trans-NiCl2N4 nodes. In the presence of C-60, NiCl2 center dot 6H(2)O and ligand 1 combine in MeOH/1,2-Cl2C6H4 to give crystalline solvated 3 [NiCl2(1)(2)]center dot C-60 which has a lamellar structure intercalated with C-60 molecules. The fullerene templates the formation of [3 + 3] bowl-shaped macrocycles which are connected through octahedral trans-NiCl2N4 nodes to [6 + 6] macrocycles generating 2-dimensional sheets.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
e-ISSN:1466-8033
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 14:12
Deposited On:01 Feb 2013 08:41

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