edoc

A matter of greasy tails : interdigitation of alkyl chains in free and coordinated 4′-(4-dodecyloxyphenyl)-4,2′:6′,4″-terpyridines

Constable, Edwin C. and Zhang, Guoqi and Housecroft, Catherine E. and Zampese, Jennifer A.. (2012) A matter of greasy tails : interdigitation of alkyl chains in free and coordinated 4′-(4-dodecyloxyphenyl)-4,2′:6′,4″-terpyridines. Inorganic Chemistry Communications, 15. pp. 113-116.

Full text not available from this repository.

Official URL: http://edoc.unibas.ch/dok/A6056196

Downloads: Statistics Overview

Abstract

The syntheses and single crystal structures of 4`-(4-dodecyloxyphenyl)-4,2`:6`,4 ``-terpyridine. 2, and [Zn-2(mu-OAc)(4)(2)(2)] are reported. Crystal packing is dominated by van der Waals interactions between fully extended alkyl chains producing lamellar structures in both compounds, and appears to be the reason for the formation of crystalline [Zn-2(mu-OAc)(4)(2)(2)] rather than a one-dimensional coordination polymer as observed for related compounds.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:1387-7003
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 14:10
Deposited On:01 Feb 2013 08:41

Repository Staff Only: item control page