Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus and Reymann, Sebastien and Schaffner, Silvia. (2008) Substituent effects in the solid-state assembly of silver(I) complexes of 4-substituted 3,6-di(2-pyridyl)pyridazines. European Journal of Inorganic Chemistry, 2008 (22). pp. 3540-3548.
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Official URL: http://edoc.unibas.ch/dok/A6055996
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Abstract
The reactions of one equivalent of silver(l) tetrafluoroborate with one equivalent of 4-R-3,6-di(2-pyridyl)pyridazine ligands(R = n-C10H21, 4-O2NC6H4, 4-MeOC6H4, 4-F3CC6H4, 4-NCC6H4, 3,5-Br2C6H3, 3,5-(MeO)(2)C6H3) in acetonitrile are reported. All complexes have been structurally characterized, and are found to belong to one of four different solid-state structure types: [AgL2][BF4], [Ag2L2][BF4](2), [Ag2L2][BF4](3)(n) and [Ag2(NCMe2L2] [BF4](2)(n). For the bulk samples of these compounds, elemental analyses are consistent with formulations of [AgL2][BF4], [Ag2L2][BF4](2), but the two polymeric complexes analyse as 1:1 Ag:L complexes. In solution, H-1 and C-13 NMR spectra reveal only one ligand environment at room temperature for each product.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable) 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Housecroft) |
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| UniBasel Contributors: | Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 1434-1948 |
| e-ISSN: | 1099-0682 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 12 Apr 2017 06:55 |
| Deposited On: | 01 Feb 2013 08:40 |
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