edoc

A one-dimensional copper(II) coordination polymer containing [Fe(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′:6′,2″-terpyridine) as an expanded 4,4′-bipyridine ligand : a hydrogen-bonded network penetrated by rod-like polymers

Beves, Jonathon E. and Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia. (2008) A one-dimensional copper(II) coordination polymer containing [Fe(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′:6′,2″-terpyridine) as an expanded 4,4′-bipyridine ligand : a hydrogen-bonded network penetrated by rod-like polymers. CrystEngComm, 10 (3). pp. 344-348.

Full text not available from this repository.

Official URL: http://edoc.unibas.ch/dok/A6056006

Downloads: Statistics Overview

Abstract

The one-dimensional coordination polymer [(H2O)(NO3)(2)CuFe(1)(2)(2)(NO3)(4)center dot 2.15MeCN center dot 5.85H(2)O](n) assembles when the pendant pyridine donors in [Fe(1)(2)](2+) (1 = 4`-(4-pyridyl)2,2`: 6`,2 ``-terpyridine) are treated with Cu(NO3)(2)center dot 3H(2)O, exemplifying [Fe(1)(2)](2+) as an expanded 4,4`-bipyridine ligand. In the solid state, the polymer chains are threaded through hydrogen-bonded macrocycles comprising coordinated and non-coordinated water molecules and nitrate ions, the macrocycles being motifs within interconnected sheets in the structure.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
e-ISSN:1466-8033
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 06:36
Deposited On:01 Feb 2013 08:40

Repository Staff Only: item control page