Bis(4′-phenyl-2,2′:6′,2″-terpyridine)ruthenium(II) : holding the {Ru(tpy)2}2+ embraces at bay

Constable, Edwin C. and Housecroft, Catherine E. and Medlycott, Elaine A. and Neuburger, Markus and Reinders, Federica and Reymann, Sebastien and Schaffner, Silvia. (2008) Bis(4′-phenyl-2,2′:6′,2″-terpyridine)ruthenium(II) : holding the {Ru(tpy)2}2+ embraces at bay. Inorganic Chemistry Communications, 11 (7). pp. 805-808.

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Official URL: http://edoc.unibas.ch/dok/A6056001

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The solid state structure of [Ru(Phtpy)(2)][PF6](2)center dot 4MeCN has been determined (Phtpy = 4`-phenyl-2,2`:6`,2 ``-terpyridine); [Ru(Phtpy)(2)](2+) cations pack into sheets by virtue of M(tpy)(2)(2) embraces, and the MeCN solvent molecules are involved in N center dot center dot center dot H-C interactions which prevent the efficient packing of adjacent sheets. Comparisons with related structures lead to some generalizations about packing motifs in salts containing [M(Phtpy)(2)](2+) or [M(pytpy)(2)](2+) cations (pytpy = 4`-pyridyl-2,2`:6`,2 ``-terpyridine).
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus
Item Type:Article, refereed
Article Subtype:Research Article
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 06:51
Deposited On:01 Feb 2013 08:40

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