Beves, Jonathon E. and Constable, Edwin C. and Decurtins, Silvio and Dunphy, Emma L. and Housecroft, Catherine E. and Keene, Tony D. and Neuburger, Markus and Schaffner, Silvia. (2008) Homoleptic metal complexes of 4'-(5-pyrimidinyl)-2,2':6',2''-terpyridine : tetrafurcated expanded ligands. CrystEngComm, 10 (8). pp. 986-990.
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Official URL: http://edoc.unibas.ch/dok/A6055998
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Abstract
With iron(II) and ruthenium(II), 4`-(5-pyrimidinyl)-2,2`: 6`,2 ``-terpyridine (L) preferentially coordinates through the tpy domain to give octahedral [ML2](2+) (M Fe, Ru) complexes. Treatment of [RuL2][PF6](2) with CuCl2 center dot 2H(2)O leads to [Ru(2)(2)][CuCl2(OH2)][CuCl3]Cl center dot 3MeCN center dot 7H(2)O(n) which exhibits a two-dimensional coordination network with copper(II) centres interconnecting [RuL2](2+) motifs. Magnetic susceptibility data for the material are consistent with a one-dimensional S = 1/2 antiferromagnetic chain.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable) 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Housecroft) |
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| UniBasel Contributors: | Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Royal Society of Chemistry |
| e-ISSN: | 1466-8033 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 12 Apr 2017 06:34 |
| Deposited On: | 01 Feb 2013 08:40 |
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