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Asymmetric hydrogenation of alkenes lacking coordinating groups

Woodmansee, David H. and Pfaltz, Andreas.. (2011) Asymmetric hydrogenation of alkenes lacking coordinating groups. Chemical Communications, 47 (28). pp. 7912-7916.

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Official URL: http://edoc.unibas.ch/dok/A5849080

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Abstract

Asymmetric hydrogenation of olefins is one of the most important reactions for the synthesis of optically active compounds, especially in industry. Chiral iridium catalysts based on P,N ligands have strongly expanded their application range. In contrast to rhodium and ruthenium diphosphine complexes they do not require the presence of a coordinating group near the C=C bond and, therefore, allow highly enantioselective hydrogenations of largely unfunctionalized alkenes.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Synthetische organische Chemie (Pfaltz)
UniBasel Contributors:Pfaltz, Andreas
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
ISSN:0022-4936
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:30 Nov 2016 10:32
Deposited On:14 Sep 2012 07:02

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