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Determining the enantioselectivity of chiral catalysts by mass spectrometric screening of their racemic forms

Ebner, Christian and Müller, Constanze A. and Markert, Christian and Pfaltz, Andreas. (2011) Determining the enantioselectivity of chiral catalysts by mass spectrometric screening of their racemic forms. Journal of the American Chemical Society, 133 (13). pp. 4710-4713.

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Official URL: http://edoc.unibas.ch/dok/A5849079

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Abstract

The enantioselectivity of a chiral catalyst can be determined from its racemic form by mass spectrometric screening of a nonequal mixture of two mass-labeled quasienantiomeric substrates. The presented method opens up new possibilities for evaluating catalyst structures that are not readily available in enantiomerically pure form.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Synthetische organische Chemie (Pfaltz)
UniBasel Contributors:Pfaltz, Andreas and Ebner, Christian
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:American Chemical Society
ISSN:0002-7863
e-ISSN:1520-5126
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 09:39
Deposited On:14 Sep 2012 07:02

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