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Proline Based P,O Iridium Complexes as Highly Selective Catalysts in the Asymmetric Hydrogenation of Trisubstituted Alkenes

Rageot, Denise and Woodmansee, David H. and Pugin, Benoît and Pfaltz, Andreas. (2011) Proline Based P,O Iridium Complexes as Highly Selective Catalysts in the Asymmetric Hydrogenation of Trisubstituted Alkenes. Angewandte Chemie International Edition, 50 (41). pp. 9598-9601.

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Official URL: http://edoc.unibas.ch/dok/A5849082

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Abstract

P,O joins the mix: P,O ligands (L1) form efficient iridium catalysts for the asymmetric hydrogenation of olefins. The proline-derived ligands lead to high enantioselectivities with several classes of alkenes, most notably with α,β-unsaturated carboxylic esters and ketones, where they match or even surpass the ee values reported for the best N,P and C,N ligands.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Synthetische organische Chemie (Pfaltz)
UniBasel Contributors:Pfaltz, Andreas and Rageot, Denise
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:1433-7851
e-ISSN:1521-3773
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 09:54
Deposited On:14 Sep 2012 07:02

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