Constable, Edwin C. and Zhang, Guoqi and Haeussinger, Daniel and Housecroft, Catherine E. and Zampese, Jennifer A.. (2011) Metallohosts with a heart of carbon. Journal of the American Chemical Society, 133 (28). pp. 10776-10779.
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Official URL: http://edoc.unibas.ch/dok/A5848947
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Abstract
Single-crystal X-ray diffraction studies have confirmed that Ni3S3-based molecular bowls prepared in one-pot reactions capture either CH2Cl2 or C-60. The nature of the pendant substituents (naphthalen-2-ylmethyl, benzyl, or ethyl) around the rim of the bowl dictates the formation of a 1:1 (bowl host-C-60 guest) or 2:1 (capsule host-C-60 guest) architecture. In CDCl3, the trimeric complexes were found to be in equilibrium with dimeric analogues. For the naphthalen-2-ylmethyl-substituted host, NMR spectroscopic titration data confirmed a 1:1 host-C-60 guest complex in 1,2-Cl2C6D4 solution.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable) 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Housecroft) 05 Faculty of Science > Departement Chemie > Chemie > Nuclear Magnetic Resonance (Häussinger) |
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| UniBasel Contributors: | Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Häussinger, Daniel |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | American Chemical Society |
| ISSN: | 0002-7863 |
| e-ISSN: | 1520-5126 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 29 Mar 2017 14:43 |
| Deposited On: | 14 Sep 2012 07:01 |
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