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Unprecedented Reactivity of Iridium(I) Secondary Phosphine Oxide Complexes: Formation of P-Coordinated Phosphinate Complexes by P−Aryl Bond Cleavage

Liniger, Marc and Gschwend, Björn and Neuburger, Markus and Schaffner, Silvia and Pfaltz, Andreas. (2010) Unprecedented Reactivity of Iridium(I) Secondary Phosphine Oxide Complexes: Formation of P-Coordinated Phosphinate Complexes by P−Aryl Bond Cleavage. Organometallics, 29 (22). pp. 5993-5958.

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Official URL: http://edoc.unibas.ch/dok/A5841370

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Abstract

Aryl−iridium(III) hydride complexes with a P-coordinated phosphinate were formed from [Ir(cod)Cl]2 and secondary phosphine oxide−oxazoline ligands under basic conditions. The structure of these complexes, whose formation involved C−P cleavage, was assigned by X-ray analysis and NMR spectroscopy.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Synthetische organische Chemie (Pfaltz)
UniBasel Contributors:Pfaltz, Andreas
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:American Chemical Society
ISSN:0276-7333
e-ISSN:1520-6041
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 13:23
Deposited On:14 Sep 2012 07:00

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